The World Nuclear Association gives about 430 reactors producing a total of about 3700 GW electricity in October 2011. Multiply by roughly 3 to get ~10 TW thermal effect.
Stockpiles are harder, and there are many estimates. Here is one historical listing http://www.johnstonsarchive.net/nuclear/nucstock-0.html, giving peaks of about 70,000 warheads, and 27,000 Mt, in the 1970's. Another estimate I found was 5000 Mt today. If we (roughly) estimate half of that to be fusion energy, those numbers need to be halved for fission content.
If we calculate from here, it would take about 1.5 years for all power plants to produce the energy of the fission part of the peak total weapons stockpile and about 4 months to match todays stockpile. If we consider that the medium age for the fuel in a reactor is about 2 years, we can estimate that the amount of long lived fission products in all reactors today is of the same order of magnitude as the long lived fission products that theoretically could have been released in a nuclear holocaust during the crazy years, and clearly above what is available today.
But then we have to add all the short lived nuclides from the weapons and activation products from both, so that is not the full picture. And of course, you have to put a nuke (or another big bomb) on a power plant to get it to release all of its content.
Hope I didn't make any bad mistakes, calculating with that many zeros is always a challenge -maybe Jim's 11 y students could check my calculations
